Photoalignment layers for liquid crystals from the di-π-methane rearrangement.

Photoalignment of liquid crystals by liquid crystals

We observed light-induced alignment of the nematic liquid crystal, 4, 4(')-n-pentylcyanobiphenyl (5CB), on a fused quartz. Irradiation of the adsorbed layer with polarized ultraviolet light produced homogeneous alignment in a 5CB-filled liquid crystal cell with the easy orientation axis perpendicular to the polarization direction. The measured anchoring energy increases with illumination up to ...

Competition between concerted and stepwise dynamics in the triplet di-π-methane rearrangement.

The molecular dynamics of the triplet-state Zimmerman di-π-methane rearrangement of dibenzobarrelene were computed with B3LYP and M06-2X density functionals. All productive quasiclassical trajectories involve sequential formation and cleavage of C-C bonds and an intermediate with lifetimes ranging from 13 to 1160 fs. Both dynamically concerted and stepwise trajectories are found. The average li...

Photoalignment possesses obvious advantages in comparison with the usually “rubbing” treatment of the substrates of liquid crystal display (LCD) cells

Photoalignment possesses obvious advantages in comparison with the usually “rubbing” treatment of the substrates of liquid crystal display (LCD) cells. The liquid crystal photoalignment is nano-technology, as the thickness of the alignment layer is about 2-15 nm. The application of the photo-alignment and photo-patterning nano technology for the new generation of photonic and display devices wi...

Comment on "photoalignment of liquid crystals by liquid crystals".

Highly sensitive photoalignment of calamitic and discotic liquid crystals assisted by axis-selective triplet energy transfer.

Highly sensitive photoalignment of liquid crystals (LCs) can be realized by axis-selective triplet energy transfer. Addition of a triplet photosensitizer (phosphorescent donor) into a photocrosslinkable polymer tethering E-cinnamate side chains ensures dramatic enhancement of photosensitivity to generate the optical anisotropy of polymer film and surface-assisted LC photoalignment. Photoirradia...